5 at%Yb3+: YNbO4 的提拉法晶体生长和光谱特性

周鹏宇; 张庆礼; 杨华军; 宁凯杰; 孙敦陆; 罗建乔; 殷绍唐

doi:10.7498/aps.61.228103

摘要

用提拉法生长了新型激光晶体5 at% Yb3+:YNbO4, 测量了它的吸收和光致发光光谱, 计算了它的吸收和发射截面, 并对其激光性能进行了评估. Yb3+:YNbO4的吸收半峰全宽为17 nm, 吸收峰位于933, 955, 974和1003 nm, 相应的吸收截面分别为0.731020, 1.8510-20, 0.8610-20和0.4410-20 cm2; 最大吸收截面值为Yb3+:YAG的两倍. 光致发光谱的发射带的中心位置处于1020 nm附近, 相应的半高宽为41 nm, 是Yb3+:YAG的3倍; Yb3+:YNbO4在955, 974, 1005, 1021和1030 nm处都有着较大的发射截面, 截面值分别为0.6910-20, 0.8610-20, 1.8110-20, 1.1110-20和0.5710-20 cm2, 最大发射截面值与Yb3+:YAG相当. Yb3+:YNbO4晶体的宽发射带有利于实现相应波长的超短脉冲和可调谐激光输出, 表明它是在这些领域非常有希望的全固态工作物质.

关键词:

Yb3+:YNbO4 /
晶体生长 /
光谱性质

Abstract

5 at%Yb3+:YNbO4 crystal is grown by Czochralski(CZ) method. Its transmission and emission spectra are measured. The absorption peaks are located at 933, 955, 974 and 1003 nm with their corresponding absorbtion cross section values 0.7310-20, 1.8510-20, 0.8610-20 and 0.4410-20 cm2; and the FWHM of 955 nm absorbtion peak is 17 nm. Its emission band centered at 1020 nm with the FWHM is 41 nm, which is over three times that of Yb3+:YAG crystal. The emission cross section values of 955, 974, 1005, 1021 and 1030 nm peaks are calculated to be 0.6910-20, 0.8610-20, 1.8110-20, 1.1110-20 and 0.5710-20 cm2, respectively, and the biggest one is comparable to that of Yb3+:YAG crystal. The laser parameters of 5 at% Yb3+:YNbO4 crystal are evaluated and the results suggest that it is a potential all-solid-state pumped laser crystal in tunable and ultrafast lasers field.

Keywords:

作者及机构信息

1.
中科院安徽光学精密机械研究所安徽省光子器件与材料重点实验室, 合肥 230031;

2.
中国科学院研究生院, 北京 100049

基金项目: 国家自然科学基金(批准号: 90922003, 50772112, 50872135, 50932005)和中科院知识创新项目(批准号: YYYJ-1002)资助的课题.

Authors and contacts

1.
The Key Laboratory of Photonic Devices and Materials, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China;

2.
Graduate University of Chinese Academy of Sciences, Beijing 100049, China

Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 90922003, 50772112, 50872135, 50932005), and the Knowledge Innovation Program of the Chinese Academy of Sciences (Grant No.YYYJ-1002).

参考文献

[1]	Qiu H W, Mao Y L, Dong J, Deng P Z, Xu J, Chen W 2002 Chinese J. Quant. Electron. 19 1 (in Chinese) [邱宏伟, 毛艳丽, 董俊, 邓佩珍, 徐军, 陈伟 2002 量子电子学报 19 1]
[2]	Zhang Q L, Xiao J Z, Sun D L, Wang A H, Yin S T 2004 Specrosc. Spect. Anal. 24 1157 (in Chinese) [张庆礼, 肖敬忠, 孙敦陆, 王爱华, 殷绍唐 2004 光谱学与光谱分析 24 1157]
[3]	Wang X D, Zhao Z W, Xu X D, Song P X, Jiang B X, Xu J, Deng P Z 2006 Acta Phys. Sin. 55 4558 (in Chinese) [王晓丹, 赵志伟, 晓东, 宋平新, 姜本学, 徐军, 邓佩珍 2006 55 4558]
[4]	Zhang H J, Jiang M H 2008 J. Inorg. Mater. 23 417 (in Chinese) [张怀金, 蒋民华 2008 无机材料学报 23 417]
[5]	Zhang Q L, Zhou W L, Liu W P, Ding L H, Luo J Q, Yin S T, Jiang H H 2010 Acta Opt. Sin. 30 849 (in Chinese) [张庆礼, 周文龙, 刘文鹏, 丁丽华, 罗建乔, 殷绍唐, 江海河 2010 光学学报 30 849]
[6]	Ding L H, Zhang Q L, Zhou W L, Liu W P, Yin S T 2009 The Pacific Rim Conference on Lasers and Electro-Optics, ShangHai, China, 2009 pp2
[7]	Gaume R, Haumesser P H, Viana B, Vivien D, Ferrand B, Aka G 2002 Opt. Mater. 19 81
[8]	Yan C, Zhao G, Zhang L, Xu J, Liang X Y, Juan D, Li W X, Pan H F, Ding L G, Zeng H P 2006 Solid State Commun. 137 451
[9]	Xue Y C, Wang Q Y, Chai L, Liu Q W, Zhao G J, Su L B, Xu X D, Xu J 2006 Acta Phys. Sin. 55 457 (in Chinese) [薛迎红, 王清月, 柴路, 刘庆文, 赵广军, 苏良碧, 徐晓东, 徐军 2006 55 457]
[10]	Jacquemet M, Jacquemet C, Janel N, Druon F, Balembois F 2005 Appl. Phys. B 80 171
[11]	Sych A M, Golub A M 1977 Russian Chem. Rev. 46 417
[12]	Choi S H, Anoop G, Suh D W, Kim K P, Lee H J, Yoo J S 2012 J. Rare Earths 30 205
[13]	Lee E Y, Kim Y J 2010 Thin Solid Films 518 E72
[14]	Nazarov M, Kim Y J, Lee E Y, Min K I, Jeong M S, Lee S W, Noh D Y 2010 J. App. Phys. 107 103104
[15]	Zhou Y, Ma Q, Lu M, Qiu M, Zhang A 2008 J. Phys. Chem. C 112 19901
[16]	Xiao X Z, Yan B 2008 J. Alloys Compd. 456 447
[17]	Xiao X Z, Yan B 2005 J. Non-cryst. Solids 351 3634
[18]	Trunov V K, Efremov V A, Velikodnyi Y A, Averina I M 1981 Kristallografiya 26 67
[19]	Zhang Q L, Yin S T, Wang Z B, Sun D L, Wan S M 2007 J. Synth. Cryst. l36 111 (in Chinese) [张庆礼, 殷绍唐, 王召兵, 孙敦陆, 万松明 2007 人工晶体学报 l36 111]
[20]	Chénais S, Duron F, Balembos F, Georges P, Brenier A, Boulon G 2003 Opt. Mater. 22 99
[21]	Gschneidner K A Jr., LeRoy E 1996 Handbook on the Physics and Chemistry of Rear Earths (Vol. 23) (Elsevier Science B. V.) p267
[22]	Payne S A, Chase L L, Smith L K 1992 IEEE. Quant. Electron. 28 2619
[23]	Zhang H W, Yang Q H, Xu J, Su L B 2007 Acta Photonica Sin. 36 286 (in Chinese) [张红伟, 杨秋红, 徐军, 苏良碧 2007 光子学报 36 286]
[24]	Song P X, Zhao Z W, Xu X D, Den P Z, Xu J 2005 Chinese J. Lasers 32 1433 (in Chinese) [宋平新, 赵志伟, 徐晓东, 邓佩珍, 徐军 2005 中国激光 32 1433]
[25]	DeLoach L D, Payne S A, Smith L K, Kway W L, Krupke W F 1994 J. Opt. Soc. Am. B 11 269
[26]	Boulon G, Collombet A, Brenier A, Cohen-Adad Marie-Thor.se, Yoshikawa A, Kheirreddine Lebbou, Lee J H, Fukuda T 2001 Adv. Funct. Mater. 11 263

施引文献

[1]	Qiu H W, Mao Y L, Dong J, Deng P Z, Xu J, Chen W 2002 Chinese J. Quant. Electron. 19 1 (in Chinese) [邱宏伟, 毛艳丽, 董俊, 邓佩珍, 徐军, 陈伟 2002 量子电子学报 19 1]
[2]	Zhang Q L, Xiao J Z, Sun D L, Wang A H, Yin S T 2004 Specrosc. Spect. Anal. 24 1157 (in Chinese) [张庆礼, 肖敬忠, 孙敦陆, 王爱华, 殷绍唐 2004 光谱学与光谱分析 24 1157]
[3]	Wang X D, Zhao Z W, Xu X D, Song P X, Jiang B X, Xu J, Deng P Z 2006 Acta Phys. Sin. 55 4558 (in Chinese) [王晓丹, 赵志伟, 晓东, 宋平新, 姜本学, 徐军, 邓佩珍 2006 55 4558]
[4]	Zhang H J, Jiang M H 2008 J. Inorg. Mater. 23 417 (in Chinese) [张怀金, 蒋民华 2008 无机材料学报 23 417]
[5]	Zhang Q L, Zhou W L, Liu W P, Ding L H, Luo J Q, Yin S T, Jiang H H 2010 Acta Opt. Sin. 30 849 (in Chinese) [张庆礼, 周文龙, 刘文鹏, 丁丽华, 罗建乔, 殷绍唐, 江海河 2010 光学学报 30 849]
[6]	Ding L H, Zhang Q L, Zhou W L, Liu W P, Yin S T 2009 The Pacific Rim Conference on Lasers and Electro-Optics, ShangHai, China, 2009 pp2
[7]	Gaume R, Haumesser P H, Viana B, Vivien D, Ferrand B, Aka G 2002 Opt. Mater. 19 81
[8]	Yan C, Zhao G, Zhang L, Xu J, Liang X Y, Juan D, Li W X, Pan H F, Ding L G, Zeng H P 2006 Solid State Commun. 137 451
[9]	Xue Y C, Wang Q Y, Chai L, Liu Q W, Zhao G J, Su L B, Xu X D, Xu J 2006 Acta Phys. Sin. 55 457 (in Chinese) [薛迎红, 王清月, 柴路, 刘庆文, 赵广军, 苏良碧, 徐晓东, 徐军 2006 55 457]
[10]	Jacquemet M, Jacquemet C, Janel N, Druon F, Balembois F 2005 Appl. Phys. B 80 171
[11]	Sych A M, Golub A M 1977 Russian Chem. Rev. 46 417
[12]	Choi S H, Anoop G, Suh D W, Kim K P, Lee H J, Yoo J S 2012 J. Rare Earths 30 205
[13]	Lee E Y, Kim Y J 2010 Thin Solid Films 518 E72
[14]	Nazarov M, Kim Y J, Lee E Y, Min K I, Jeong M S, Lee S W, Noh D Y 2010 J. App. Phys. 107 103104
[15]	Zhou Y, Ma Q, Lu M, Qiu M, Zhang A 2008 J. Phys. Chem. C 112 19901
[16]	Xiao X Z, Yan B 2008 J. Alloys Compd. 456 447
[17]	Xiao X Z, Yan B 2005 J. Non-cryst. Solids 351 3634
[18]	Trunov V K, Efremov V A, Velikodnyi Y A, Averina I M 1981 Kristallografiya 26 67
[19]	Zhang Q L, Yin S T, Wang Z B, Sun D L, Wan S M 2007 J. Synth. Cryst. l36 111 (in Chinese) [张庆礼, 殷绍唐, 王召兵, 孙敦陆, 万松明 2007 人工晶体学报 l36 111]
[20]	Chénais S, Duron F, Balembos F, Georges P, Brenier A, Boulon G 2003 Opt. Mater. 22 99
[21]	Gschneidner K A Jr., LeRoy E 1996 Handbook on the Physics and Chemistry of Rear Earths (Vol. 23) (Elsevier Science B. V.) p267
[22]	Payne S A, Chase L L, Smith L K 1992 IEEE. Quant. Electron. 28 2619
[23]	Zhang H W, Yang Q H, Xu J, Su L B 2007 Acta Photonica Sin. 36 286 (in Chinese) [张红伟, 杨秋红, 徐军, 苏良碧 2007 光子学报 36 286]
[24]	Song P X, Zhao Z W, Xu X D, Den P Z, Xu J 2005 Chinese J. Lasers 32 1433 (in Chinese) [宋平新, 赵志伟, 徐晓东, 邓佩珍, 徐军 2005 中国激光 32 1433]
[25]	DeLoach L D, Payne S A, Smith L K, Kway W L, Krupke W F 1994 J. Opt. Soc. Am. B 11 269
[26]	Boulon G, Collombet A, Brenier A, Cohen-Adad Marie-Thor.se, Yoshikawa A, Kheirreddine Lebbou, Lee J H, Fukuda T 2001 Adv. Funct. Mater. 11 263

[1]	孙贵花, 张庆礼, 罗建乔, 王小飞, 谷长江. Pr, Yb, Ho:GdScO₃晶体生长及光谱性能. , 2024, 73(5): 059801. doi: 10.7498/aps.73.20231362
[2]	孙贵花, 张庆礼, 罗建乔, 王小飞, 谷长江. Pr,Yb,Ho:GdScO₃晶体生长及光谱性能研究. , 2023, 0(0): . doi: 10.7498/aps.72.20231362
[3]	孙贵花, 张庆礼, 罗建乔, 孙敦陆, 谷长江, 郑丽丽, 韩松, 李为民. Ti:MgAl₂O₄激光晶体的提拉法生长及性能表征. , 2020, 69(1): 014210. doi: 10.7498/aps.69.20191150
[4]	高松, 王欣, 范小康, 李科峰, 廖梅松, 胡丽丽. Tm3+掺杂锗碲酸盐玻璃的近2 μm光谱性质. , 2014, 63(24): 247801. doi: 10.7498/aps.63.247801
[5]	姜大朋, 苏良碧, 徐军, 唐慧丽, 吴锋, 郑丽和, 王庆国, 郭鑫, 邹宇琦. Cr,Mg:GSGG 晶体生长、光谱性能及Cr4+形成机理的研究. , 2012, 61(3): 038102. doi: 10.7498/aps.61.038102
[6]	邢辉, 陈长乐, 金克新, 谭兴毅, 范飞. 相场晶体法模拟过冷熔体中的晶体生长. , 2010, 59(11): 8218-8225. doi: 10.7498/aps.59.8218
[7]	刘丽莎, 吕树臣, 孙江亭. Er3+/Yb3+共掺TeO2-WO3-Bi2O3玻璃的光谱性质和上转换发光. , 2010, 59(9): 6637-6641. doi: 10.7498/aps.59.6637
[8]	牛睿祺, 董慧茹, 王云平. 非线性光学晶体4-(4-二甲基氨基苯乙烯基)甲基吡啶对甲基苯磺酸盐的制备与性能研究. , 2007, 56(7): 4235-4241. doi: 10.7498/aps.56.4235
[9]	贾相华, 吕树臣. Er3+及Er3+/Yb3+共掺铋酸盐玻璃光谱性质研究. , 2007, 56(8): 4971-4976. doi: 10.7498/aps.56.4971
[10]	杨秋红, 曾智江, 徐军, 苏良碧. Mg，Ti共掺Al2O3透明多晶陶瓷光谱性能研究. , 2006, 55(6): 2726-2729. doi: 10.7498/aps.55.2726
[11]	李涛, 张勤远, 姜中宏. Ce3+对Er3+/Yb3+共掺氟磷酸盐玻璃光谱性质的影响. , 2006, 55(8): 4298-4303. doi: 10.7498/aps.55.4298
[12]	王英伟, 王自东, 程灏波. 新型激光晶体Yb:KY(WO4)2的结构与光谱. , 2006, 55(9): 4803-4808. doi: 10.7498/aps.55.4803
[13]	杨秋红, 曾智江, 徐军, 丁君, 苏良碧. Cr4+在Al2O3多晶体中的光谱性能研究. , 2006, 55(8): 4166-4169. doi: 10.7498/aps.55.4166
[14]	汪国年, 戴世勋, 张军杰, 胡丽丽, 姜中宏. Yb:铅锌镧碲酸盐玻璃的热学、光谱和激光性质. , 2005, 54(4): 1854-1858. doi: 10.7498/aps.54.1854
[15]	曾智江, 杨秋红, 徐军. Cr3+:Al2O3透明多晶陶瓷光谱特性分析. , 2005, 54(11): 5445-5449. doi: 10.7498/aps.54.5445
[16]	柳祝平, 唐景平, 胡丽丽, 姜中宏. Cr3+,Yb3+,Er3+共掺磷酸盐铒玻璃转镜调Q激光性质研究. , 2005, 54(9): 4422-4426. doi: 10.7498/aps.54.4422
[17]	李涛, 张勤远, 冯洲明, 赵纯, 姜中宏. 碱金属和碱土金属氟化物对掺Er3+氟磷酸盐玻璃光谱性质的影响. , 2005, 54(10): 4926-4932. doi: 10.7498/aps.54.4926
[18]	沈祥, 聂秋华, 徐铁峰, 高媛. Er3+/Yb3+共掺碲钨酸盐玻璃的光谱性质和热稳定性的研究. , 2005, 54(5): 2379-2384. doi: 10.7498/aps.54.2379
[19]	柳祝平, 胡丽丽, 张德宝, 戴世勋, 祁长鸿, 姜中宏. Yb3+,Er3+离子共掺磷酸盐铒玻璃的Judd-Ofelt光谱参数与光谱性质. , 2002, 51(11): 2629-2634. doi: 10.7498/aps.51.2629
[20]	张龙, 林凤英, 胡和方. Yb3+掺杂四磷酸盐玻璃光谱研究. , 2001, 50(7): 1378-1384. doi: 10.7498/aps.50.1378

计量

文章访问数: 13915
PDF下载量: 651
被引次数: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

搜索

留言板