分子动力学模拟方法在非线性光学中的应用

赵珂; 刘朋伟; 韩广超

doi:10.7498/aps.60.124216

摘要

有机分子非线性光学材料在频率转换、电光调制和双光子吸收等方面具有重要的应用.介绍了近年来分子动力学模拟方法在有机分子非线性光学性质理论研究中的主要应用,包括电场极化效应、局域场因子、非线性极化率和双光子吸收等.此外,结合最新的科研工作,介绍了分子动力学模拟方法在溶剂效应和聚集效应研究中发挥的重要作用.

关键词:

Organic nonlinear optical molecular materials have a number of important applications in frequency transformation, electrooptic modulation, two-photon absorption and so on. In this paper, we introduce the main applications of molecular dynamics simulation in theoretical study on nonlinear optical properties of organic molecules, including the electric field poling effects, the local field factors, the nonlinear susceptibilities, and the two-photon absorption. In addition, the important roles played by molecular dynamics simulation in the study of solvent and aggregation effects are also illustrated in combination with the recent research.

Keywords:

作者及机构信息

1.
山东师范大学物理与电子科学学院,济南 250014

基金项目: 国家自然科学基金(批准号:10904085,10974121)和山东省自然科学基金(批准号:ZR2010AZ002)资助的课题.

Authors and contacts

1.
College of Physics and Electronics, Shandong Normal University, Jinan 250014, China

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施引文献

[1]	Denk W, Strickler J H, Webb W W 1990 Science 248 73
[2]	Khler R H, Cao J, Zipfel W R, Webb W W, Hansen M R 1997 Science 276 2039
[3]
[4]	Ehrlich J E, Wu X L, Lee I Y, Hu Z Y, Roeckel H, Marder S R, Perry J 1997 Opt. Lett. 22 1843
[5]
[6]
[7]	He G S, Zhao C F, Bhawalkar J D, Prasad P N 1995 Appl. Phys. Lett. 67 3703
[8]	Bhawalkar J D, He G S, Prasad P N 1996 Rep. Prog. Phys. 59 1041
[9]
[10]	Parthenopouslos D A, Rentzepis P M 1989 Science 245 843
[11]
[12]	Dvornikov A S, Rentzepis P M 1995 Opt. Commun. 119 341
[13]
[14]	Chung S J, Kim K S, Lin T C, He G S, Swiatkiewicz J, Prasad P N 1999 J. Phys. Chem. B 103 10741
[15]
[16]
[17]	Chung S J, Lin T C, Kim K S, He G S, Swiatkiewicz J, Prasad P N, Baker G A, Bright F V 2001 Chem. Mater. 13 4071
[18]
[19]	Adronov A, Frchet J M J, He G S, Kim K S, Chung S J, Swiatkiewicz J, Prasad P N 2000 Chem. Mater. 12 2838
[20]
[21]	Drobizhev M, Karotki A, Rebane A, Spangler C W 2001 Opt. Lett. 26 1081
[22]	Yang W J, Kim D Y, Kim C H, Jeong M Y, Lee S K, Jeon S J, Cho B R 2004 Org. Lett. 6 1389
[23]
[24]
[25]	Meng F, Li B, Qian S, Chen K, Tian H 2004 Chem. Lett. 33 470
[26]	Drobizhev M, Karotki A, Dzenis Y, Rebane A, Suo Z, Spangler C W 2003 J. Phys. Chem. B 107 7540
[27]
[28]	Porres L, Mongin O, Katan C, Charlot M, Pons T, Mertz J, Blanchard-Dense M 2004 Org. Lett. 6 47
[29]
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[31]
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[84]
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[87]
[88]
[89]	Tu Y, Luo Y, gren H 2005 J. Phys. Chem. B 109 16730
[90]
[91]	Tu Y, Luo Y, gren H 2006 J. Phys. Chem. B 110 8971
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[93]
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[96]
[97]	Reis H, Makowska-Janusika M, Papadopoulos M G 2004 J. Phys. Chem. B 108 8931
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[99]
[100]
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[102]
[103]	Reis H, Papadopoulos M G, Theodorou D N 2001 J. Chem. Phys. 114 876
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[105]
[106]	Nielsena C B, Christiansenc O, Mikkelsen K V, Kongstede J 2007 J. Chem. Phys. 126 154112
[107]
[108]	Yamaguchi Y, Yokomichi Y, Yokoyama S, Mashiko S 2001 J. Mol. Struct. (Theochem.) 545 187
[109]
[110]
[111]	Murugan N A, Kongsted J, Rinkevicius Z, gren H 2010 Proc. Natl. Acad. Sci. USA 107 16453
[112]
[113]	Zhao K, Tu Y, Luo Y 2009 J. Phys. Chem. B 113 10271
[114]	Liu K, Wang Y H, Tu Y, gren H, Luo Y 2008 J. Phys. Chem. B 112 4387
[115]
[116]
[117]	Paterson M J, Kongsted J, Christiansen O, Mikkelsend K V, Nielse C B 2006 J. Chem. Phys. 125 184501
[118]	Zhao K, Liu P W, Wang C K, Luo Y 2010 J. Phys. Chem. B 114 10814
[119]
[120]	Car R, Parrinello M 1985 Phys. Rev. Lett. 55 2471
[121]
[122]	Murugan N A, Kongsted J, Rinkevicius Z, Aidas K, gren H 2010 J. Phys. Chem. B 114 13349
[123]
[124]
[125]	Murugan N A, Kongsted J, Rinkevicius Z, gren H 2011 Phys. Chem. Chem. Phys. 13 1290
[126]	Murugan N A, Jha P C, Rinkevicius Z, Ruud K, gren H 2010 J. Chem. Phys. 132 234508
[127]
[128]
[129]	Meng S, Ma J 2008 J. Phys. Chem. B 112 4313
[130]
[131]	Meng S, Ma J, Jiang Y S 2007 J. Phys. Chem. B 111 4128
[132]	Wrthner F, Schmidt J, Stolte M, Wortmann R 2006 Angew. Chem. Int. Ed. 45 3842
[133]

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