-
用电弧炉熔炼方法制备了Ｓｍ2Ｆｅ17-xＭxＣ1.5（Ｍ＝Ｇａ，Ｓｉ）化合物，研究了它们的形成、结构与磁性。实验结果表明，用Ｇａ替代Ｆｅ，当２≤ｘ≤６时，可形成Ｔｈ2Ｚｎ17型单相化合物，而Ｓｉ的替代仅在ｘ＝２时为单相结构。居里温度随Ｇａ含量的增加从ｘ＝２时的６３３Ｋ下降到ｘ＝６时的３５１Ｋ，Ｓｍ2Ｆｅ15Ｓｉ2Formation, structure and magnetic properties of Ｓｍ2Ｆｅ17-xＭxＣ1.5（Ｍ＝Ｇａ，Ｓｉ） compounds prepared by arc-melting were studied. The Ｓｍ2Ｆｅ17-xGaxＣ1.5(3≤x≤6) carbides crystallize in the rhombohedral Ｔｈ2Ｚｎ17-type structure and the single-phase compund of Ｓｍ2Ｆｅ17-xSixＣ1.5 can only be obtained as x is 2. It is found that the Curie temperature of Ｓｍ2Ｆｅ17-xGaxＣ1.5 compounds decreases monotonically with increasing Ga concentration x from 633K for x=2 to 351K for x=6，and the Tc of Ｓｍ2Ｆｅ15Si2Ｃ1.5 compound is 578K. All compounds studied in this work exhibit an easy c-axis anisotropy at room temperature. The anisotropy field of Ｓｍ2Ｆｅ14Ga3Ｃ1.5 and Ｓｍ2Ｆｅ15Si2Ｃ1.5 compounds is found td be 90 and 115 kOe, respectively. A room-temperature coercivity of 16 kOe is obtained in rapidly quenched Ｓｍ2Ｆｅ15Si2Ｃ1.5 alloy prepared at。speed of 25 m/s.
计量
- 文章访问数: 7184
- PDF下载量: 513
- 被引次数: 0
留言板
尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!
| 姓名 | |
|---|---|
| 邮箱 | |
| 手机号码 | |
| 标题 | |
| |
下载:
