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在含锰1.7%的γ-铁中观察到因含碳而引起的内耗峰。当振动频率约为2周/秒时,内耗峰出现在240℃左右。这个内耗峰由于含碳量的增加而升高,由于在较高温度保温而降低。根据内耗测量所得的激活能是34,000±2000卡/克分子,与碳在γ-铁中的激活能(宏观扩散实验的数据)相合,由此可知所观测的内耗峰是由于碳在γ-铁(含锰1.7%)中的应力感生微扩散所引起来的。根据内耗测量的数据求出了碳在200—250℃的温度范围内在γ-铁中扩散的扩散系数。在logD—l/T坐标上,这些数据与宏观扩散实验所测得的在1000—1200℃的扩散系数坐落在一条直线上。所观测的内耗峰高度似乎与含碳量的二次方成正比,这表示在应力感生扩散过程中直接参加元跳动的乃是两个碳原子。由此可以提出一个产生内耗峰的初步模型:由于点阵中有空穴存在,两个碳原子很容易构成一个在各方向引起不同畸变的原子对,由于这个原子对在应力作用下的转动而产生内耗。In γ-iron (containing 1.7% of Mn) an internal friction peak was observed around 240℃with a frequency of vibration of about 2 cycles per second. The height of the peak was found to increase with an increase of the carbon content and was found to decrease when the specimen was annealed at an elevated temperature. The activation energy associated with this peak was found to be 34,000±2,000 calories permole which is close to the activation energy of diffusion of carbon in y-iron determined in macro-diffusion experiments. It is concluded, thus, the observed internal frictionpeak is associated with the stress-induced diffusion of carbon in y-iron.The coefficient of diffusion D of carbon in y-iron in the temperature range of 200-260℃ was calculated according to data given by internal friction measurements. When plotted with logD against 1/T, these values of D were found to lie on the same straight line with those values of D in the temperature range of 1000-1200℃ determined in macro-diffusion experiments.The height of internal friction peak appeared to vary with the square of the carbon content in the specimen. This seems to indicate that two carbon atoms are participating in the elementary act associated with the stress-induced diffusion. A preliminary model for the observed internal friction peak was suggested thereupon: Owing to the presence of holes (vacancies) in the crystal lattice, two carbon atoms are apt to form an atomic-pair and this pair produces lattice distortions which are different along three crystallographic directions. Rotation of such an atomic-pair under the action of stress gives rise to internal friction.
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