直接键合的三结太阳能电池研究

彭红玲; 张玮; 孙利杰; 马绍栋; 石岩; 渠红伟; 张冶金; 郑婉华

doi:10.7498/aps.63.178801

摘要

本文研制了直接键合的三结GaInP/GaAs/InGaAsP太阳电池. 直接键合技术可以减少晶格不匹配的材料在外延生长过程中产生的线位错和面缺陷，将缺陷限制在界面几十纳米的薄层而不向内扩散，是未来实现高效多结电池的发展趋势之一. 此类电池国内鲜有报道. 本文键合三结电池的键合界面采用p+GaAs/n+InP结构，得到电池开路电压3.0 V，在电池结构没有优化的情况下获得效率24%，表面未做减反膜. 开路电压表明三结电池实现了串联，为单片集成的高效多结电池提供了新的途径. 对实验结果进行了分析并给出了改进措施.

关键词:

Abstract

The multi-junction bonding GaInP/GaAs/InGaAsP solar cell was developed. Bonding technology can reduce dislocations and defects produced in the epitaxial growth process of the lattice mismatch materials, and the defects are restricted within dozens of nanometer layers at the interface without spreading into the inner layers. Bonding solar cell is one of the efficient developing trends in the future. The solar cell interface uses p+ GaAs/n+ InP tunneling junction, and the open circuit voltage is greater than 3.0V. The efficiency is 24% when the structural parameter is not optimized and the anti-reflective film is not prepared. Open circuit voltage shows that the two solar sub cells are connected in series. Results are analyzed and the improvement measures are given. This bonding technology provides a new way for monolithic integration high efficient multi-junction cells.

Keywords:

作者及机构信息

1.
中国科学院半导体研究所集成光电子学国家重点实验室, 北京 100083;

2.
中国航天科技集团公司上海空间电源研究所, 上海 200245

基金项目: 中国科学院知识创新工程重要方向项目（批准号：09JA041001）资助的课题.

Authors and contacts

1.
State Key Laboratory on Integrated Optoelectronics, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, China;

2.
Shanghai Institute of Space Power Sources, CASC, Shanghai 200245, China

Funds: Project supported the by Important Direction Item of the Knowledge innovation Project of Chinese Academy of Sciences (Grant No. 09JA041001).

参考文献

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施引文献

[1]	Law D C, King R R, Yoon H, Archer M J, Boca A, Fetzer C M, Mesropian S, Isshiki T, Haddad M, Edmondson K M, Bhusari D, Yena J, Sherif R A, Atwater H A, Karama N H 2010 Sol. Energy Mater. Sol. Cells 94 1314
[2]	Tatavarti R, Wibowo A, Martin G, Tuminello F, Youtsey C, Hillier G, Pan N, Wanlass M W, Romero M 2010 Photovoltaic Specialists Conference (PVSC) 35th IEEE Honolulu Hawaii, USA, June 20-25, 2010, p002125
[3]
[4]
[5]	Zahler J M, Tanabe K, Ladous C, Pinnington T, Newman F D, Atwater H A 2007 Appl. Phys. Lett. 91 012108
[6]
[7]	Archer M J, Law D C, Mesropian S, Haddad M, Fetzer C M, Ackerman A C, Ladous C, King R R, Atwater H A 2008 Appl. Phys. Lett. 92 103503
[8]
[9]	Schone J, Dimroth F, Bett A W, Tauzin A, Jaussaud C, Roussin J C 2006 Photovoltaic Energy Conversion Conference Record of the 2006 IEEE 4th World Conference IEEE Waikoloa, USA, May 7-12, 2006 p776
[10]	Law D C, Bhusari D M, Mesropian S, Boisvert J C, Hong W D, Boca A, Larrabee D C, Fetzer C M, King R R, Karam N H 2009 Photovoltaic Specialists Conference (PVSC) 34th IEEE Philadelphia, Pennsylvania USA, June 7-12, 2009 p002237
[11]
[12]
[13]	Bhusari D, Law D, Woo R, Boisvert J, Mesropian S, Larrabee D, Hong W, Karam N 2011 Photovoltaic Specialists Conference (PVSC) 37th IEEE Seattle, Washington USA, June 19-24, 2011 p001937
[14]
[15]	Tanabe K, Watanabe K, Arakawa Y 2012 www.nature.com/scientific reports srep00349 1
[16]	Chiu P T, Law D C, Woo R L, Singer S B, Bhusari D, Hong W D, Zakaria A, Boisvert J, Mesropian S, King R R, Karam N H 2014 IEEE Journal of Photovoltaics 4 493
[17]
[18]
[19]	Chen M B, Cui R Q, Wang L X, Zhang Z W, Lu J F, Chi W Y 2004 Acta Phys. Sin. 53 3632 (in Chinese)[陈鸣波, 崔容强, 王亮兴, 张忠卫, 陆剑峰, 池卫英 2004 53 3632]
[20]	Tu J L, Zhang W, Zhao H L, Li Y, Fu R, Zhao P K 2011 Journal of Yunnan Normal University 31 9 (in Chinese)[涂洁磊, 张玮, 赵恒利, 李烨, 付蕊, 赵沛坤2011云南师范大学学报 31 9]
[21]
[22]
[23]	Ma Shao dong, Peng Hongling, Chen Wei, Jiang Bin, Zheng Wanhua 2011 Materials for Renewable Energy Environment (ICMREE) International Conference 2011 Shanghai, China, May 20-22, 2011 p234
[24]	Wang J Z, Ye J S, Huang Q L, Xu X, Li D M, Meng Q B, Yang G Zh 2014 Chin. Phys. B 23 044211
[25]
[26]
[27]	Zhang Y, Shan Z F, Cai J J, Wu H Q, Li J C, Chen K X, Lin Z W, Wang X W 2013 Acta Phys. Sin. 62 158802 (in Chinese)[张永, 单智发, 蔡建九, 吴洪清, 李俊承, 陈凯轩, 林志伟, 王向武 2013 62 158802]
[28]
[29]	Sun L J, Zhang M Y, Fang X, Chen K J, Zhang W, Chen M J, Lu J F 2013 Photovoltaic Specialists Conference (PVSC) {39th IEEE Tampa, Florida, USA, June 16-21, 2013 p2832
[30]	Tanabe K, Aiken D J, Wanlass M W, Morral A F, Atwater H A 2006 Photovoltaic Energy Conversion Conference Record of the 2006 IEEE 4th World Conference: IEEE Waikoloa, USA, May 712, 2006 p768
[31]
[32]
[33]	Tanabe K, Morral A F, Atwater H A, Aiken D J, Wanlass M W 2006 Appl. Phys. Lett. 89 102106

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