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The Raman optical activity (ROA) of (R)-(-)-1,3-butanediol was described through the analysis of bond polarizability and differential bond polarizability, which were elucidated by Raman and ROA spectral intensities, respectively. Analysis shows that during the Raman process, the charge flows from the (six) rings formed by H16 (or H15) O6C3C2C1O5 to the peripheral OH and CH bonds. The analysis also shows that the signs of differential bond polarizabilities associated with the rings inside and outside are opposite. This means that the chiral asymmetry of this molecule is fairly distinct.
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Keywords:
- Raman optical activity /
- bond polarizability /
- differential bond polarizability /
- (R)-(-)-1,3-Butanediol
[1] Matsuyama A, Kobayashi Y 1994 Biosci Biotech Biochem. 58 1148
[2] Rami A. Abdel-Rahem 2012 Colloid Plym Sci. 290 907
[3] Serge Gueldry, Jean Bralet 1995 Metabolic Brain Disease. 10 293
[4] Barron L D, Buckingham A D 1971 Mol. Phys. 20 1111
[5] Barren L D, Bogaard M P, Buckingham A D 1973 J. Am. Chem. Soc. 95 603
[6] Buckinghem A D 1994 Faraday Discuss 99 1
[7] Nafie L A, Che D 1994 Adv. Chem. Phys. 85 105
[8] Barron L D, Hecht L, Bell A F, Wilson G 1996 Appl. Spectrosc. 50 619
[9] Tian B, Wu G, Liu G 1987 J. Chem. Phys. 87 7300
[10] Chantry G W 1971 The Raman Effect vo1.1 (New York: Marcel Dekker) p49
[11] Hoffmann R 1963 J. Chem. Phys. 39 1397
[12] Shen H, Wu G Z, Wang P J 2012 Chin. Phys. B 21 123301
[13] Zhao Y M, Wang P J, Fang Y, Wu G Z 2012 Acta Phys. Sin. 62 240201 (in Chinese) [赵彦牧, 王培杰, 方炎, 吴国祯 2012 62 240201]
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[1] Matsuyama A, Kobayashi Y 1994 Biosci Biotech Biochem. 58 1148
[2] Rami A. Abdel-Rahem 2012 Colloid Plym Sci. 290 907
[3] Serge Gueldry, Jean Bralet 1995 Metabolic Brain Disease. 10 293
[4] Barron L D, Buckingham A D 1971 Mol. Phys. 20 1111
[5] Barren L D, Bogaard M P, Buckingham A D 1973 J. Am. Chem. Soc. 95 603
[6] Buckinghem A D 1994 Faraday Discuss 99 1
[7] Nafie L A, Che D 1994 Adv. Chem. Phys. 85 105
[8] Barron L D, Hecht L, Bell A F, Wilson G 1996 Appl. Spectrosc. 50 619
[9] Tian B, Wu G, Liu G 1987 J. Chem. Phys. 87 7300
[10] Chantry G W 1971 The Raman Effect vo1.1 (New York: Marcel Dekker) p49
[11] Hoffmann R 1963 J. Chem. Phys. 39 1397
[12] Shen H, Wu G Z, Wang P J 2012 Chin. Phys. B 21 123301
[13] Zhao Y M, Wang P J, Fang Y, Wu G Z 2012 Acta Phys. Sin. 62 240201 (in Chinese) [赵彦牧, 王培杰, 方炎, 吴国祯 2012 62 240201]
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