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类胡萝卜素是含有9个CC共轭双键的短链多烯类生物分子. 特殊的分子结构, 使其不仅在光采集, 光防护, 防癌, 抗癌等生物学领域有重要应用, 而且在分子导线, 光开关, 滤光器等光电器件研制中也有重要的非生物学应用. 本文对它的分子光谱进行研究和总结, 结果表明, 类胡萝卜素具有宽带荧光, 将其用于荧光增强受激拉曼散射可以获得宽带受激拉曼散射; 电子能隙随温度降低而收缩, 电子吸收光谱红移, 这特性使它能研制优质半导体元件; 极大的拉曼活性和三阶非线性系数, CC键基频拉曼散射截面可以比普通分子大10个数量级, 和频、倍频拉曼散射强度也很高, 低温下与基频强度比可达0.5. 类胡萝卜素分子的这些光谱特性对多烯类分子结构、性能研究及其在非生物学中的应用有重要参数价值.Carotenoid is a short-chain polyene biomolecule of 9 CC conjugate double-bonds. Due to its special structure carotenoid is used not only in photoprotection and anti-cancer, but also in molecule wires, light switch, and light filter. In this paper molecule spectra of carotenoid are studied. The carotenoid has the broadband fluorescence, the broadband stimulated Raman scattering is obtained when the fluorescence of carotenoid is used to enhance stimulated Raman scattering. Electron energy gap of carotenoid becomes narrow with temperature decreasing, and absorption spectra are red-shifted. These characteristics can make the carotenoid a high-quality semiconductor component. Raman active is intensive and the 3rd order optical nonlinear coefficient is large. The Raman scattering cross section of CC bond is about 10 orders of magnitude larger than that of common molecule. The Raman scattering intensity of overtone is intensive: the ratio of overtone to basic frequency is around 0.5 at low temperature. These spectrum characteristics of carotenoid are significant for studying polyene molecule structure, property and non-biology domain.
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Keywords:
- carotenoid /
- Raman spectrum /
- UV-VIS absorption spectrum
[1] Qu G N, Li D F, Li Z L, Ouyang S L, Li Z W, Gao S Q, Zhou M, Men Z W, Wang W W, Yang J G, 2010 Acta Phys. Sin. 59 242 (in Chinese) [曲冠男, 李东飞, 李占龙, 欧阳顺利, 里佐威, 高淑琴, 周密, 门志伟, 王微微, 杨建戈 2010 59 242]
[2] Hoskins L C, Alexander V 1977 Anal. Chem. 49 695
[3] Hayashi H, Brack T L, Noguchi T, Tasumi M, Atkinson G H 1991 J. Phys. Chem. 95 6797
[4] Zhao X H, Ma F, Wu Y S, Ai X C, Zhang J P 2008 Acta Phys. Sin. 57 298 (in Chinese) [赵晓辉, 马菲, 吴义室, 艾希成, 张建平 2008 57 298]
[5] Ma Y P, Bao P, Yu Z H 2006 Chemical Research In Chinese Universities 27 1526 (in Chinese) [马艳平, 包鹏, 虞忠衡 2006 高等学校化学学报 27 1526]
[6] Zuo J, Li Z W, Tian Y J, Chen J, Gao S Q, Lu G H 2007 Acta Phys. Sin. 56 890 (in Chinese) [左剑, 里佐威, 田艳杰, 陈健, 高淑琴, 陆国会 2007 56 890]
[7] Kaminskii A A, Rhee H, Eichler H J, Bohaty L, Becker P, Takaichi K 2008 Laser Phys. Lett. 5 304
[8] Garruthers T F, Duling I N, Horowitz M, Menyuk C R 2000 Opt. Lett. 25 153
[9] Kirsh V A, Hayes R B, Mayne S T 2006 J. Natl. Cancer Inst. 98 245
[10] Chu B S, Ichikawa S, Kanafusa S 2007 J. Am. Oil Chem. Soc. 84 1053
[11] Sugisaki M, Fujiwara M, Nair S V, Ruda H E, Cogdell R J, Hashimoto H 2009 Phys. Rev. B 80 035118
[12] Wang W W, Li L, Li Z L, Sun C L, Ouyang S L, Xu D P, Qu G N, Li Z W, Gao S Q, Cao J S, Hao F L, Zhou Q 2010 Chemical Research In Chinese Universities 31 1864 (in Chinese) [王微微, 李亮, 李占龙, 孙成林, 欧阳顺利, 许大鹏, 曲冠男, 里佐威, 高淑琴, 曹军胜, 郜峰利, 周强 2010 高等学校化学学报 31 1864]
[13] OuYang S L, Sun C L, Zhou M, Li D F, Wang W W, Qu G N, Li Z W, Gao S Q, Yang J G 2010 Science China: Physics, Mechanics & Astronomy 53 1646
[14] Saxenaa A, Kivsharb Y S, Bishopa A R 2001 Synthetic Met. 116 45
[15] Zuo H Y, Gao J, Yang J G 2007 Spectroscopy and Spectral Analysis 27 552] (in Chinese) [左浩毅, 高洁, 杨经国 2007 光谱学与光谱分析 27 552]
[16] Men Z W, Fang W H, Sun X P, Li Z W, Cao B, Gao S Q, Lu G H 2009 Science China 9 556 (in Chinese) [门志伟, 房文汇, 孙秀平, 里佐威, 曹彪, 高淑琴, 陆国会 2009 中国科学 9 556]
[17] Zhong X Q, Yang J G, Ha Y Q, Meng J P, Li Y Q, Luan C L 2000 High Power Laser and Particle Beams 12 172 (in Chinese) [钟先琼, 杨经国, 哈元清, 蒙建平, 黎源倩, 栾崇林 2000 强激光与粒子数 12 172]
[18] Wang W W 2011 Ph. D. Dissertation (Jilin University) (in Chinese) [王微微 2011 硕士学位论文 (吉林大学)]
[19] Dudik J M, Johnson R, Asher S A 1985 J. Chem. Phys. 82 1732
[20] Paraschuk D Y, Golovnin I V, Smekhova A G, Kobryanskii V M 2002 JETP Lett. 76 669
[21] Tian Y J, Zuo J, Zhang L Y, Li Z W, Gao S Q, Lu G H 2007 Appl. Phys. B 87 727
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[1] Qu G N, Li D F, Li Z L, Ouyang S L, Li Z W, Gao S Q, Zhou M, Men Z W, Wang W W, Yang J G, 2010 Acta Phys. Sin. 59 242 (in Chinese) [曲冠男, 李东飞, 李占龙, 欧阳顺利, 里佐威, 高淑琴, 周密, 门志伟, 王微微, 杨建戈 2010 59 242]
[2] Hoskins L C, Alexander V 1977 Anal. Chem. 49 695
[3] Hayashi H, Brack T L, Noguchi T, Tasumi M, Atkinson G H 1991 J. Phys. Chem. 95 6797
[4] Zhao X H, Ma F, Wu Y S, Ai X C, Zhang J P 2008 Acta Phys. Sin. 57 298 (in Chinese) [赵晓辉, 马菲, 吴义室, 艾希成, 张建平 2008 57 298]
[5] Ma Y P, Bao P, Yu Z H 2006 Chemical Research In Chinese Universities 27 1526 (in Chinese) [马艳平, 包鹏, 虞忠衡 2006 高等学校化学学报 27 1526]
[6] Zuo J, Li Z W, Tian Y J, Chen J, Gao S Q, Lu G H 2007 Acta Phys. Sin. 56 890 (in Chinese) [左剑, 里佐威, 田艳杰, 陈健, 高淑琴, 陆国会 2007 56 890]
[7] Kaminskii A A, Rhee H, Eichler H J, Bohaty L, Becker P, Takaichi K 2008 Laser Phys. Lett. 5 304
[8] Garruthers T F, Duling I N, Horowitz M, Menyuk C R 2000 Opt. Lett. 25 153
[9] Kirsh V A, Hayes R B, Mayne S T 2006 J. Natl. Cancer Inst. 98 245
[10] Chu B S, Ichikawa S, Kanafusa S 2007 J. Am. Oil Chem. Soc. 84 1053
[11] Sugisaki M, Fujiwara M, Nair S V, Ruda H E, Cogdell R J, Hashimoto H 2009 Phys. Rev. B 80 035118
[12] Wang W W, Li L, Li Z L, Sun C L, Ouyang S L, Xu D P, Qu G N, Li Z W, Gao S Q, Cao J S, Hao F L, Zhou Q 2010 Chemical Research In Chinese Universities 31 1864 (in Chinese) [王微微, 李亮, 李占龙, 孙成林, 欧阳顺利, 许大鹏, 曲冠男, 里佐威, 高淑琴, 曹军胜, 郜峰利, 周强 2010 高等学校化学学报 31 1864]
[13] OuYang S L, Sun C L, Zhou M, Li D F, Wang W W, Qu G N, Li Z W, Gao S Q, Yang J G 2010 Science China: Physics, Mechanics & Astronomy 53 1646
[14] Saxenaa A, Kivsharb Y S, Bishopa A R 2001 Synthetic Met. 116 45
[15] Zuo H Y, Gao J, Yang J G 2007 Spectroscopy and Spectral Analysis 27 552] (in Chinese) [左浩毅, 高洁, 杨经国 2007 光谱学与光谱分析 27 552]
[16] Men Z W, Fang W H, Sun X P, Li Z W, Cao B, Gao S Q, Lu G H 2009 Science China 9 556 (in Chinese) [门志伟, 房文汇, 孙秀平, 里佐威, 曹彪, 高淑琴, 陆国会 2009 中国科学 9 556]
[17] Zhong X Q, Yang J G, Ha Y Q, Meng J P, Li Y Q, Luan C L 2000 High Power Laser and Particle Beams 12 172 (in Chinese) [钟先琼, 杨经国, 哈元清, 蒙建平, 黎源倩, 栾崇林 2000 强激光与粒子数 12 172]
[18] Wang W W 2011 Ph. D. Dissertation (Jilin University) (in Chinese) [王微微 2011 硕士学位论文 (吉林大学)]
[19] Dudik J M, Johnson R, Asher S A 1985 J. Chem. Phys. 82 1732
[20] Paraschuk D Y, Golovnin I V, Smekhova A G, Kobryanskii V M 2002 JETP Lett. 76 669
[21] Tian Y J, Zuo J, Zhang L Y, Li Z W, Gao S Q, Lu G H 2007 Appl. Phys. B 87 727
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