调制光/电作用下染料敏化太阳电池中电荷传输和界面转移研究

刘伟庆; 寇东星; 胡林华; 黄阳; 姜年权; 戴松元

doi:10.7498/aps.59.5141

摘要

详细讨论了染料敏化太阳电池(DSC)在稳态光照射或外加偏压下电荷的传输和转移过程,以及在调制光/电作用下电池的频率响应特点.通过电化学阻抗谱、光电化学阻抗谱、强度调制光电流谱和强度调制光电压谱等四种频谱光电测试手段,对DSC中TiO2薄膜电子传输和界面转移的相关时间常数进行测量.详细分析和比较了电荷的传输及转移过程对时间常数的影响.结果表明,在低光强或低偏压下电荷传输和转移过程对时间常数影响较小,但在高光强或高偏压下对电子寿命影响明显.

关键词:

Abstract

In the present work, the processes of charge transport and electron transfer in dye-sensitized solar cell (DSC) under the stable illumination or forward bias were discussed, and the frequency response characteristic to the small perturbation of the light or voltage in DSC was also interpreted. The electron transit time and electron lifetime were investigated by electrochemical impedance spectroscopy (EIS), photoelectrochemical impedance spectroscopy (PEIS), intensity modulated photocurrent spectroscopy (IMPS) and intensity modulated photovoltage spectroscopy (IMVS). The time constants determined by different measurement techniques were compared. The results showed that the process of charge transport and electron transfer has no significant influence on the time constants under low bias or low light intensity, and this process affected predominately the electron lifetime under high bias or high light intensity.

Keywords:

作者及机构信息

(1)温州大学物理与电子信息学院,温州 325035; (2)中国科学院等离子体物理研究所,中国科学院新型薄膜太阳电池重点实验室,合肥 230031

基金项目: 国家重点基础研究发展计划(批准号: 2006CB202600)、国家高技术研究发展计划(批准号: 2009AA050603)、中国科学院知识创新工程重要方向性项目(批准号: KGCX2-YW-326)和国家自然科学基金(批准号:20703046)资助的课题.

Authors and contacts

(1)College of Physics & Electronic Information Engineering, Wenzhou University, Wenzhou 325035, China; (2)Key Laboratory of Novel Thin Film Solar Cells of Chinese Academy of Sciences, Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031, China

参考文献

[1]	Schlichthorl G, Huang S Y, Sprague J, Frank A J 1997 J. Phys. Chem. B 101 8141
[2]	Dloczik L, Ileperuma O, Lauermann I, Peter L M, Ponomarev E A, Redmond G, Shaw N J, Uhlendorf I 1997 J. Phys. Chem. B 101 10281
[3]	Oregan B, Gratzel M 1991 Nature 353 737
[4]	Hu L H, Dai S Y, Weng J, Xiao S F, Sui Y F, Huang Y, Chen S H, Kong F T, Pan X, Liang L Y, Wang K J 2007 J. Phys. Chem. B 111 358
[5]	Dai J, Hu L H, Liu W Q, Dai S Y 2008 Acta Phys. Sin. 57 5310 (in Chinese) [戴俊、胡林华、刘伟庆、戴松元 2008 57 5310]
[6]	Liang L Y, Dai S Y, Hu L H, Dai J, Liu W Q 2009 Acta Phys. Sin. 58 1338 (in Chinese) [梁林云、戴松元、胡林华、戴俊、刘伟庆 2009 58 1338]
[7]	Hao Y Z, Yang M Z, Yu C, Cai S M 1998 Acta Phys. Chim. Sin. 14 309 (in Chinese) [郝彦忠、杨迈之、余赪、蔡生民 1998 物理化学学报 14 309]
[8]	Liang L Y, Dai S Y, Fang X Q, Hu L H 2008 Acta Phys. Sin. 57 1956(in Chinese)[梁林云、戴松元、方霞琴、胡林华 2008 57 1956]
[9]	Zakeeruddin S M, Grtzel M 2009 Adv. Funct. Mater. 19 2187
[10]	Wang H, Liu Y, Xu H M, Dong X, Shen H, Wang Y H, Yang H X 2009 Renew. Energ. 34 1635
[11]	Zhang Y, Zhao Y, Cai N, Xiong S Z 2008 Acta Phys. Sin. 57 5806 (in Chinese) [张苑、赵颖、蔡宁、熊绍珍 2008 57 5806]
[12]	Meng Q B, Fu C H, Einaga Y, Gu Z Z, Fujishima A, Sato O 2002 Chem. Mater. 14 83
[13]	Chen X L, Xue J M, Zhang D K, Sun J, Ren H Z, Zhao Y, Geng X H 2007 Acta Phys. Sin. 56 1563 (in Chinese) [陈新亮、薛俊明、张德坤、孙建、任慧志、赵颖、耿新华 2007 56 1563]
[14]	Chen C Y, Wang M K, Li J Y, Pootrakulchote N, Alibabaei L, Ngoc-le C H, Decoppet J D, Tsai J H, Gratzel C, Wu C G, Zakeeruddin S M, Gratzel M 2009 ACS. Nano 3 3103
[15]	Bisquert J 2002 J. Phys. Chem. B 106 325
[16]	Bisquert J, Zaban A, Salvador P 2002 J. Phys. Chem. B 106 8774
[17]	Koide N, Islam A, Chiba Y, Han L Y 2006 J. Photochem. Photobiol. A 182 296
[18]	Han L Y, Koide N, Chiba Y, Islam A, Mitate T 2006 C. R. Chim. 9 645
[19]	Wang Q, Moser J E, Gratzel M 2005 J. Phys. Chem. B 109 14945
[20]	Peter L M, Wijayantha K G U 2000 Electrochim. Acta 45 4543
[21]	Liu W Q, Hu L H, Huo Z P, Dai S Y 2009 Prog. Chem. 21 1085 (in Chinese) [刘伟庆、胡林华、霍志鹏、戴松元 2009 化学进展 21 1085]
[22]	Peter L M, Duffy N W, Wang R L, Wijayantha K G U 2002 J. Electroanal. Chem. 524 127
[23]	Kern R, Sastrawan R, Ferber J, Stangl R, Luther J 2002 Electrochim. Acta 47 4213
[24]	He C, Zhao L, Zheng Z, Lu F 2008 J. Phys. Chem. C 112 18730
[25]	Huang S Y, Schlichthorl G, Nozik A J, Gratzel M, Frank A J 1997 J. Phys. Chem. B 101 2576
[26]	Adachi M, Sakamoto M, Jiu J T, Ogata Y, Isoda S 2006 J. Phys. Chem. B 110 13872
[27]	Fabregat-Santiago F, Bisquert J, Garcia-Belmonte G, Boschloo G, Hagfeldt A 2005 Sol. Energy Mater. Sol. Cells 87 117
[28]	van de Lagemaat J, Park N G, Frank A J 2000 J. Phys. Chem. B 104 2044

施引文献

[1]	Schlichthorl G, Huang S Y, Sprague J, Frank A J 1997 J. Phys. Chem. B 101 8141
[2]	Dloczik L, Ileperuma O, Lauermann I, Peter L M, Ponomarev E A, Redmond G, Shaw N J, Uhlendorf I 1997 J. Phys. Chem. B 101 10281
[3]	Oregan B, Gratzel M 1991 Nature 353 737
[4]	Hu L H, Dai S Y, Weng J, Xiao S F, Sui Y F, Huang Y, Chen S H, Kong F T, Pan X, Liang L Y, Wang K J 2007 J. Phys. Chem. B 111 358
[5]	Dai J, Hu L H, Liu W Q, Dai S Y 2008 Acta Phys. Sin. 57 5310 (in Chinese) [戴俊、胡林华、刘伟庆、戴松元 2008 57 5310]
[6]	Liang L Y, Dai S Y, Hu L H, Dai J, Liu W Q 2009 Acta Phys. Sin. 58 1338 (in Chinese) [梁林云、戴松元、胡林华、戴俊、刘伟庆 2009 58 1338]
[7]	Hao Y Z, Yang M Z, Yu C, Cai S M 1998 Acta Phys. Chim. Sin. 14 309 (in Chinese) [郝彦忠、杨迈之、余赪、蔡生民 1998 物理化学学报 14 309]
[8]	Liang L Y, Dai S Y, Fang X Q, Hu L H 2008 Acta Phys. Sin. 57 1956(in Chinese)[梁林云、戴松元、方霞琴、胡林华 2008 57 1956]
[9]	Zakeeruddin S M, Grtzel M 2009 Adv. Funct. Mater. 19 2187
[10]	Wang H, Liu Y, Xu H M, Dong X, Shen H, Wang Y H, Yang H X 2009 Renew. Energ. 34 1635
[11]	Zhang Y, Zhao Y, Cai N, Xiong S Z 2008 Acta Phys. Sin. 57 5806 (in Chinese) [张苑、赵颖、蔡宁、熊绍珍 2008 57 5806]
[12]	Meng Q B, Fu C H, Einaga Y, Gu Z Z, Fujishima A, Sato O 2002 Chem. Mater. 14 83
[13]	Chen X L, Xue J M, Zhang D K, Sun J, Ren H Z, Zhao Y, Geng X H 2007 Acta Phys. Sin. 56 1563 (in Chinese) [陈新亮、薛俊明、张德坤、孙建、任慧志、赵颖、耿新华 2007 56 1563]
[14]	Chen C Y, Wang M K, Li J Y, Pootrakulchote N, Alibabaei L, Ngoc-le C H, Decoppet J D, Tsai J H, Gratzel C, Wu C G, Zakeeruddin S M, Gratzel M 2009 ACS. Nano 3 3103
[15]	Bisquert J 2002 J. Phys. Chem. B 106 325
[16]	Bisquert J, Zaban A, Salvador P 2002 J. Phys. Chem. B 106 8774
[17]	Koide N, Islam A, Chiba Y, Han L Y 2006 J. Photochem. Photobiol. A 182 296
[18]	Han L Y, Koide N, Chiba Y, Islam A, Mitate T 2006 C. R. Chim. 9 645
[19]	Wang Q, Moser J E, Gratzel M 2005 J. Phys. Chem. B 109 14945
[20]	Peter L M, Wijayantha K G U 2000 Electrochim. Acta 45 4543
[21]	Liu W Q, Hu L H, Huo Z P, Dai S Y 2009 Prog. Chem. 21 1085 (in Chinese) [刘伟庆、胡林华、霍志鹏、戴松元 2009 化学进展 21 1085]
[22]	Peter L M, Duffy N W, Wang R L, Wijayantha K G U 2002 J. Electroanal. Chem. 524 127
[23]	Kern R, Sastrawan R, Ferber J, Stangl R, Luther J 2002 Electrochim. Acta 47 4213
[24]	He C, Zhao L, Zheng Z, Lu F 2008 J. Phys. Chem. C 112 18730
[25]	Huang S Y, Schlichthorl G, Nozik A J, Gratzel M, Frank A J 1997 J. Phys. Chem. B 101 2576
[26]	Adachi M, Sakamoto M, Jiu J T, Ogata Y, Isoda S 2006 J. Phys. Chem. B 110 13872
[27]	Fabregat-Santiago F, Bisquert J, Garcia-Belmonte G, Boschloo G, Hagfeldt A 2005 Sol. Energy Mater. Sol. Cells 87 117
[28]	van de Lagemaat J, Park N G, Frank A J 2000 J. Phys. Chem. B 104 2044

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