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乾根—别卡曾经分析过原子晶体中的极化子问题。文中指出,其中弹性形变的考虑是不正确的,而且“绝热型”的极化子,在例如Ge,Si等原子晶体中存在的可能性是十分微小的。以微扰论为基础的计算证明,电子引起的局部体积变化发生在半径≈λ的范围内,λ是以声速运动的电子的德布罗意波长。局部体变的数值等於E/(α+4/3μ)(E为形变势常数,α和μ分别为体变和切变模量)。局部体变还在样品中引起一个均匀的形变,两者合起来使样品体积改变E/α。具体的分析证明,在类氢的杂质能级中的电子使样品体积产生同样的体积变化。这个效应是相当大的;例如,在Ge和Si这样的晶体中,效应甚至可以舆实验所观测到Ⅲ,Ⅴ族杂质原子的体积效应相比拟。导带中低速电子能量的改变约等於(电子质量/原胞质量)(E/(kΘD))E;在Ge晶体中,如果E=1—10电子伏,能量改变是0.001—0.1电子伏。相应的有效质量改变是1/1000—1/10电子质量。在类氢杂质能级中,电子能量改变远比上值为小;理论上电子—晶格互作用有着可能致使类氢能级自发电离。The only previous work known to us on the polaron problem in atomic lattices gives a result which would mean that polarons of the adiabatic type (in the first approximation, a self-trapping state with static deformation) should exist in crystals such as Ge and Si. (The method used in dealing with the elastic energy is shown to be in error.) We have reconsidered the problem and found that most probably the reverse is the case. The problem is then investigated on the basis of the perturbation theory. It is shown that the volume change, strongest at the electron, extends essentially as far as one de Broglie wave length of an electron moving with the speed of sound; beyond this distance, the elastic displacement is of the 1/r2 type. The volume changearound the electron totals E/(a+4/3μ)(E being the deformation potential constant, a and μ beingrespectively the bulk and shear molulus). This local volume change induces a uniform strain in the specimen, the two effects together gives a total volume change E/a. The elastic deformation caused by an electron in a hydrogen-like impurity state is also considered. The total volume effect turns out to be identical with the above. The effect is quite considerable; for instance, it can be comparable with the observed volume change caused by a Ⅲ,Ⅴ type of impurity atom in a Ge or Si lattice. Energy change of a low speed electron in a conduction band is roughly ((electron mass)/(mass of lattice cell))(E/(kΘD))E which amounts to 0.001-0.1 eV for E=1-10 eV in Ge. The corresponding change in effective mass is 1/1000-1/10 electron mass. The energy change for an electron in a hydrogen-like impurity state is much smaller, it thus appears theoretically possible that the electron-lattice interaction may render an impurity state unstable against ionization!
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